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Thanks for the speedy response jomifl,
The E drive shows as a hard drive in 'my computer', the 150GB storage that I supposedly have on this computer seems to be split almost equally between the C & E drives, although everything seems to have been automatically stored by default onto the C drive. and I have almost 73GB free on the E drive. However, if I right click a file then highlight 'move to...' the E drive doesn't show as an option.